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From CapFAQ

How do I get my calendar events to sync with my Google Calendar?

When entering in events into the Captivate's calendar, be sure to change the Calendar option from My Calendar to your Google account. You can go back and change existing events' setting. Unfortunately there's no way to make this the default with the stock calendar at this time, however third-party calendars such as Jorte and Gemini do support changing the default. Be sure to check them out if you desire this to see if they meet your needs.